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Petrochemical / Coal Chemical

Petrochemical / Coal Chemical

The petrochemical industry faces “three high” challenges: high emission concentration, high volatility and high risk. The coal chemical industry highlights the characteristics of “two high and one strong” : high proportion of sulfur and nitrogen pollutants (H2S+NH₃>50%) and strong corrosion (phenolic substances pH 2.5-3.5).

In-depth analysis of typical emission sources in petrochemical industry

• Process emission
Catalytic cracking regenerated flue gas containing C3-C5 olefin, polycyclic aromatic hydrocarbons, flue gas temperature 650-750℃
Continuous reforming regenerated exhaust gas benzene/toluene/xylene concentration 5,000-20,000mg/m³, hydrogen content >85%
Hydrocracking cycle gas containing C1-C4 light hydrocarbons, methane accounted for 60-80%, pressure fluctuation 8-15MPa
• Dissipation of storage and transportation system
Floating top tank seal failure edge breathing loss rate 0.5-1.2kg/h, BTEX daily emissions up to 50-80kg
Oil and gas escape the peak oil and gas concentration is 1.2-1.5× saturated vapor pressure, ~500-800g/m³
• Volatilization of wastewater treatment
Grease trap surface volatilization sulfide accounts for 18-25%
Aeration tank gas stripping discharge chlorine-containing VOCs 50-150mg/m³, gas-water ratio 15-30:1

Depth analysis of typical emission sources in coal chemical industry

• Coal gasification purification section
Low temperature methanol washing tail gas methanol vapor load 0.8–1.5%, H₂S escape concentration 3,000–6,000 mg/m³
Sulfur recovery device leakage Klaus process tail gas contains COS 50–150 mg/m³, CS₂ 80–200 mg/m³
• Coal tar processing section
Tar distillation tower roof gas benzo[a]pyrene concentration reached 200 μg/m³, naphthalene series accounted for 40–60%
Hydrofining exhaust gas phenolic substance concentration 800–1,500 mg/m³, ammonia content 200–500 ppm
• High concentration wastewater treatment section
Phenol ammonia recovery unit H₂S concentration peak and valley value 300–1,200 ppm, pH value 2.8–3.5
Biochemical treatment tank volatile fatty acid (VFA) discharge flux 0.5–1.2 kg/h, mercaptan odor intensity >5,000

Key treatment difficulties

Multi-component coordination to solve the problem
Dynamic working condition adaptability challenge
Material tolerance limitations
Safety risk control requirements
Energy efficiency economic balance

CADAIR Technology System Construction Path

💧 Closed collection of waste water tank
Floating cap + nitrogen seal system

🔥 Combustion system
RTO / RCO / CO

🛡️ Corrosion-resistant material application
Duplex steel equipment + PTFE lining

🌫️ Sulfur nitrogen co-treatment
Chemical washing + SNCR / SCR

♻️ Preheat recovery treatment
Waste heat boiler

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