• Process emission | |
Catalytic cracking regenerated flue gas | containing C3-C5 olefin, polycyclic aromatic hydrocarbons, flue gas temperature 650-750℃ |
Continuous reforming regenerated exhaust gas | benzene/toluene/xylene concentration 5,000-20,000mg/m³, hydrogen content >85% |
Hydrocracking cycle gas | containing C1-C4 light hydrocarbons, methane accounted for 60-80%, pressure fluctuation 8-15MPa |
• Dissipation of storage and transportation system | |
Floating top tank seal failure | edge breathing loss rate 0.5-1.2kg/h, BTEX daily emissions up to 50-80kg |
Oil and gas escape | the peak oil and gas concentration is 1.2-1.5× saturated vapor pressure, ~500-800g/m³ |
• Volatilization of wastewater treatment | |
Grease trap surface volatilization | sulfide accounts for 18-25% |
Aeration tank gas stripping discharge | chlorine-containing VOCs 50-150mg/m³, gas-water ratio 15-30:1 |
• Coal gasification purification section | |
Low temperature methanol washing tail gas | methanol vapor load 0.8–1.5%, H₂S escape concentration 3,000–6,000 mg/m³ |
Sulfur recovery device leakage | Klaus process tail gas contains COS 50–150 mg/m³, CS₂ 80–200 mg/m³ |
• Coal tar processing section | |
Tar distillation tower roof gas | benzo[a]pyrene concentration reached 200 μg/m³, naphthalene series accounted for 40–60% |
Hydrofining exhaust gas | phenolic substance concentration 800–1,500 mg/m³, ammonia content 200–500 ppm |
• High concentration wastewater treatment section | |
Phenol ammonia recovery unit | H₂S concentration peak and valley value 300–1,200 ppm, pH value 2.8–3.5 |
Biochemical treatment tank | volatile fatty acid (VFA) discharge flux 0.5–1.2 kg/h, mercaptan odor intensity >5,000 |
Technical features:contains a variety of pollutants with significant differences in physical and chemical properties, such as low boiling point esters + high boiling point PAHs+ solid particles, there are azeotrope, adsorption competition and other interactions
Technical bottleneck:the efficiency of traditional process is attenuated
Fluctuation characteristics:quantized concentration fluctuation range, air volume variation range, temperature transient rate >20℃/min
Engineering impact:system resistance to shock load (such as RTO responds to 300% concentration change in 5 minutes), equipment fatigue damage (starting and stopping 5 times a day leads to thermal stress accumulation)
Corrosion medium:Identify the type of corrosion factor (e.g. HS2>200ppm, Cl⁻>1,000mg/m³), pH extreme value (e.g. Phenol wastewater pH<3)
Failure data:equipment life decay rate (such as carbon steel corrosion rate >0.5mm/ year in sulfur-containing waste gas)
Explosion risk:LEL concentration and operating conditions overlap degree
Toxicity control:concentration of acute toxic substances (e.g. Acrylonitrile <0.5mg/m³), limit of carcinogens (benzene <0.5mg/m³)
Energy consumption index:unit processing power consumption, heat recovery efficiency
Cost conflict:high removal demand and operating costs