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Petrochemical / Coal Chemical

Petrochemical / Coal Chemical

The petrochemical industry faces “three high” challenges: high emission concentration, high volatility and high risk. The coal chemical industry highlights the characteristics of “two high and one strong” : high proportion of sulfur and nitrogen pollutants (H2S+NH₃>50%) and strong corrosion (phenolic substances pH 2.5-3.5).

In-depth analysis of typical emission sources in petrochemical industry

• Process emission
Catalytic cracking regenerated flue gas containing C3-C5 olefin, polycyclic aromatic hydrocarbons, flue gas temperature 650-750℃
Continuous reforming regenerated exhaust gas benzene/toluene/xylene concentration 5,000-20,000mg/m³, hydrogen content >85%
Hydrocracking cycle gas containing C1-C4 light hydrocarbons, methane accounted for 60-80%, pressure fluctuation 8-15MPa
• Dissipation of storage and transportation system
Floating floor tank seal failure edge breathing loss rate 0.5-1.2kg/h, BTEX daily emissions up to 50-80kg
Oil and gas escape the peak oil and gas concentration is 1.2-1.5× saturated vapor pressure, ~500-800g/m³
• Volatilization of wastewater treatment
Volatilization on the surface of the oil-separating tank sulfide accounts for 18-25%
Aeration tank gas stripping discharge chlorine-containing VOCs 50-150mg/m³, gas-water ratio 15-30:1

Depth analysis of typical emission sources in coal chemical industry

• Coal gasification purification section
Rectisol tail gas methanol vapor load 0.8–1.5%, H₂S escape concentration 3,000–6,000 mg/m³
Sulfur recovery device leakage Klaus process tail gas contains COS 50–150 mg/m³, CS₂ 80–200 mg/m³
• Coal tar processing section
Tar distillation overhead gas benzo[a]pyrene concentration reached 200 μg/m³, naphthalene series accounted for 40–60%
Hydrofining exhaust gas phenolic substance concentration 800–1,500 mg/m³, ammonia content 200–500 ppm
• High concentration wastewater treatment section
Phenol ammonia recovery unit H₂S concentration peak and valley value 300–1,200 ppm, pH value 2.8–3.5
Biochemical treatment tank volatile fatty acid (VFA) emission rate 0.5–1.2 kg/h, mercaptan odor intensity >5,000

Key treatment difficulties

Multi-component collaborative treatment
Challenges in Adaptability to Dynamic Working Conditions
Material tolerance limitations
Safety risk control requirements
Balance between energy efficiency and economy

Construction path of CADAIR technical system

💧 Closed collection of waste water pool
Floating cap + nitrogen blanketing system

🔥 Combustion system
RTO / RCO / CO

🛡️ Application of anti-Corrosion material
Duplex stainless steel equipment +PTFE lining

🌫️ Co-treatment of Sulfur and NOx
Chemical scrub +SNCR/SCR

♻️ Waste heat recovery
Waste heat boiler/HRSG

CADAIR related products

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